This concise introduction to boranes and metalloboranes employs an
informal and straightforward style. The author establishes facts
first, and rationalization and theories follow. Ideas of cluster
bonding are presented, and the author surveys different approaches
to the bonding in clusters, emphasizing the use of frontier
molecule orbitals and the construction of clusters from fragments.
The application of spectroscopic techniques to the elucidation of
cluster structure is discussed, with an emphasis on multinuclear
NMR spectroscopy. The second edition includes an update on
structural data for boranes and their anions. Sections on
spectroscopy and the reactivity of metalloboranes have been
slightly expanded and references have been updated.
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