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Prato Reaction (Paperback) Loot Price: R722
Discovery Miles 7 220
Prato Reaction (Paperback): Lambert M. Surhone, Mariam T. Tennoe, Susan F. Henssonow

Prato Reaction (Paperback)

Lambert M. Surhone, Mariam T. Tennoe, Susan F. Henssonow

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Loot Price R722 Discovery Miles 7 220 | Repayment Terms: R67 pm x 12*

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High Quality Content by WIKIPEDIA articles The Prato reaction in fullerene chemistry describes the functionalization of fullerenes and nanotubes with azomethine ylides in a 1,3-dipolar cycloaddition. The amino acid sarcosine reacts with paraformaldehyde when heated at reflux in toluene to an ylide which reacts with a double in a 6,6 ring position in a fullerene in a 1,3-dipolar cycloaddition to yield a N-methylpyrrolidine derivative or pyrrolidinofullerene or pyrrolidino 3,4:1,2]] 60]fullerene in 82% yield. In one application a liquid fullerene is obtained when the pyrrolidone substituent is a 2,4,6-tris(alkyloxy)phenyl group although a small amount of solvent is still required. This method is also used in the functionalization of single wall nanotubes. When the amino acid is modified with a glycine chain the resulting nanotubes are soluble in common solvents such chloroform and acetone. Another characteristic of the treated nanotubes is their larger aggregate dimensions compared to untreated nanotubes.

General

Imprint: Betascript Publishing
Country of origin: United States
Release date: August 2010
First published: August 2010
Editors: Lambert M. Surhone • Mariam T. Tennoe • Susan F. Henssonow
Dimensions: 152 x 229 x 5mm (L x W x T)
Format: Paperback - Trade
Pages: 88
ISBN-13: 978-6132322470
Categories: Books > Science & Mathematics > Chemistry
Books > Science & Mathematics > Chemistry > General
LSN: 6132322477
Barcode: 9786132322470

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