In the continuing discovery of new catalytic reactions, compounds
that contain two very different metal centers, in particular, have
attracted considerable interest. The synthesis, structure and
chemistry of these compounds called heterobimetallic complexes have
grown steadily over the past few decades. In complexes where one
metal is from the main group and the other is a transition metal,
the modification of the dynamic behavior and chemical reactivity of
the complex over that of the monometallic species makes
heterobimetallic complexes synthetically useful. In this book, the
synthesis, characterization, heterobimetallic complexes and dynamic
behavior of the organotin compounds of cycloheptatriene and
cyclooctatetraene are described. The applications in physical
chemistry brought about by the special longchain structure of some
of these complexes are also studied.
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