Thermal Decomposition and Combustion of Explosives and Propellants (Hardcover)

This unique monograph investigates the synthesis, properties and processing of energetic materials and propellant compositions. The thermal decomposition of energetic compounds, such as aliphatic and aromatic nitrocompounds, nitramines, nitroethers, organic azides and difluoroamines, polynitrous heterocycles, and onium salts of different acids, the most important components of modern propellants, are given. The kinetics and mechanisms of chemical reactions for both real and model compounds are presented and the classic problem of the dependence of explosive activity on molecular structure is examined.

New methods for a formal kinetic description of decay of condensed substances, the determination of the energy of bond rupture in polyfunctional compounds and the theory of solid-phase reactions are also given. Applications to problems of predicting the stability, compatibility, and the stabilization of explosives and propellant components are included.

The book will be of interest to graduate students, researchers and professionals in industry interested in chemical kinetics and the combustion of energetic materials.